Connections Between Molecular Photoionization and Electron-molecule Scattering with Emphasis on Shape Resonances

Connections Between Molecular Photoionization and Electron-molecule Scattering with Emphasis on Shape Resonances
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Download or read book Connections Between Molecular Photoionization and Electron-molecule Scattering with Emphasis on Shape Resonances written by and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Most of our detailed information on the spectroscopy and dynamics of the electronic continuum of molecules is based on the complementary probes - photoionization and electron scattering. Though usually studied separately, it is most useful to appreciate the connections between these two processes since our understanding of one is often the key to interpreting or even generating new results in the other. We approach this subject in two steps. First, we very briefly outline the well-established connections, e.g., the Bethe-Born theory and comparisons of isoelectronic systems. Then we focus on a point of contact - the role of shape resonances in molecular photoionization and electron-molecule scattering - for which a substantial amount of new information has become available. Specific topics include mapping of resonances from the neutral (h.nu. + molecule) to the negative ion (e + molecule) system, angular distributions, and interaction with vibration.

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